Slow magnetic relaxation in a 3D network of cobalt(II) citrate cubanes.
نویسندگان
چکیده
The synthesis, structure and magnetic properties of a 3D network based on {Co₄(cit)₄}⁸⁻ (H₄cit = citric acid) cubane units linked by octahedral Co(II) centres is reported.
منابع مشابه
A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour.
A newly prepared 3-D polymer of cobalt citrate cubanes bridged by high-spin Co(ii) centres displays both single-molecule magnet (SMM) behaviour and magnetic ordering. Triple interpenetration of the 3-D diamondoid polymers yields a crystalline solid with channels that host cations and free water molecules, with the SMM behaviour of the Co4O4 cores preserved. The octahedrally coordinated Co(ii) b...
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عنوان ژورنال:
- Dalton transactions
دوره 39 20 شماره
صفحات -
تاریخ انتشار 2010